Browsing by Author "Kara, N."

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Citation - WoS: 1
Citation - Scopus: 1
Calculation of the spin-lattice relaxation time and the activation energy near the IV–III phase transition in pyridinium fluorosulfonate (C5NH6)FSO3
(Taylor & Francis Ltd, 2022) Kara, N.; Kiraci, A.; Yurtseven, Hamit; 42475
The spin-lattice relaxation time T-1(H) for protons nuclei is calculated in term of the pseudospin-phonon (PS) coupled and the energy fluctuation (EF) models close to the IV-III solid-solid phase transition of T-C = 235 K in (C5NH6)FSO3. This calculation was performed by associating the observed second moment of the H-1 as the order parameter below k and the disorder parameter above T-C. Values of the activation energy for the cation reorientation in this crystal are also deduced by using both models. In addition, the observed dielectric permittivity of this crystal is analyzed within the framework of the Landau theory and values of the spontaneous polarization (P-s) are determined as a function of temperature. The normalized values of P-s are used in the PS and EF models to extract the activation energy for the reorientation of the dipole moment of this compound arising from cation-anion interaction. Our results show that the PS and EF models can describe the observed behavior of the spin-lattice relaxation time adequately for the IV-III solid-solid transition in (C5NH6)FSO3.
Citation - WoS: 0
Citation - Scopus: 1
Phenomenological approaches on the Nd3+ doped ferroelectric LaBGeO5
(Taylor & Francis Ltd, 2021) Kara, N.; Kiracı, Ali; Kiraci, A.; Yurtseven, Hamit; Ortak Dersler Bölümü
Two phenomenological models, namely the compressible Ising model and Landau model, have been used to analyze the specific heat and the dielectric constant data, respectively for the pure and Nd3+ doped LaBGeO5 (LBG) crystals. The critical exponent of the specific heat was extracted in both ferroelectric and paraelectric phases of the crystals studied here within the temperature intervals of [T - T-C vertical bar < 4 K. The extracted values of the critical exponent were then used to predict some thermodynamic quantities such as the enthalpy, entropy, and the Gibbs free energy. Regarding the analysis of dielectric constant data within the framework of the Landau theory, the observed values of the birefringence were associated with the order parameter below the transition temperature T-c. The Landau coefficients a(0) and a(4) were determined. Our results indicate a second-order phase transition mechanism.