Browsing by Author "Yurtseven, Hamit"

Now showing 1 - 9 of 9

Citation - WoS: 2
Citation - Scopus: 3
Analysis of the Integrated Intensity of the Central Peaks Calculated as a Function of Temperature in the Ferroelectric Phase of Lithium Tantalate
(Vinca inst Nuclear Sci, 2018) Yurtseven, Hamit; Kiraci, Ali; 42475; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
The integrated intensity of the central peak is calculated as a function of temperature in the ferroelectric phase (T < T-C) of nearly stoichiometric LiTaO3. This calculation is performed using the temperature dependence of the order parameter obtained from the mean field theory at temperatures lower than the transition temperature T-C (T-C = 963 K) of this crystal. The calculated values of the order parameter (squared) are fitted to the integrated intensity of the central peaks as observed from the Raman and Brillouin scattering experiments as reported in the literature in the ferroelectric phase of nearly stoichiometric LiTaO3. Our results are in good agreement with the observed behavior of LiTaO3 crystal. Because of the applications of LiTaO3 in several academic disciplines including the material science and thermal science, it is beneficial to investigate dynamic properties of this crystal such as the damping constant, inverse relaxation time and the activation energy as also we studied here.
Citation - WoS: 1
Citation - Scopus: 1
Calculation of the Spin-Lattice Relaxation Time and the Activation Energy Near the Iv-Iii Phase Transition in Pyridinium Fluorosulfonate (C5nh6)fso3
(Taylor & Francis Ltd, 2022) Kara, N.; Kiraci, A.; Yurtseven, Hamit; 42475; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
The spin-lattice relaxation time T-1(H) for protons nuclei is calculated in term of the pseudospin-phonon (PS) coupled and the energy fluctuation (EF) models close to the IV-III solid-solid phase transition of T-C = 235 K in (C5NH6)FSO3. This calculation was performed by associating the observed second moment of the H-1 as the order parameter below k and the disorder parameter above T-C. Values of the activation energy for the cation reorientation in this crystal are also deduced by using both models. In addition, the observed dielectric permittivity of this crystal is analyzed within the framework of the Landau theory and values of the spontaneous polarization (P-s) are determined as a function of temperature. The normalized values of P-s are used in the PS and EF models to extract the activation energy for the reorientation of the dipole moment of this compound arising from cation-anion interaction. Our results show that the PS and EF models can describe the observed behavior of the spin-lattice relaxation time adequately for the IV-III solid-solid transition in (C5NH6)FSO3.
Citation - WoS: 8
Citation - Scopus: 8
Damping Constant (Linewidth) and the Relaxation Time of the Brillouin La Mode for the Ferroelectric-Paraelectric Transition in Pbzr1-Xtixo3
(Ieee-inst Electrical Electronics Engineers inc, 2016) Kiraci, Ali; Yurtseven, Hamit; 42475; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
The damping constant (linewidth) of the longitudinal acoustic (LA) mode is calculated as a function of temperature using the observed Brillouin frequencies of this mode from the literature for the ferroelectric-paraelectric transition (T-C = 657 K) in PbZr1-xTixO3 (x = 0.45). For this calculation of the damping constant, the pseudospin-phonon coupled model and the energy fluctuation model are used by fitting to the observed data for the Brillouin frequencies of the LA mode in the ferroelectric (T < T-C) and paraelectric (T > T-C) phases of this compound (x = 0.45). Values of the activation energy are deduced for both ferroelectric and paraelectric phases. The relaxation time is also obtained by means of fitting to the observed data from the literature for the inverse relaxation time at various temperatures in the paraelectric phase of PbZr1-xTixO3. The temperature dependences of the damping constant and of the relaxation time with the values of the activation energy that we have calculated indicate that the pseudospin-phonon coupled model and the energy fluctuation model are capable of describing the ferroelectric-paraelectric transition (T-C = 657 K) in PbZr1-xTixO3 (x = 0.45) adequately.
Citation - WoS: 4
Citation - Scopus: 4
Order-Disorder Transition in the Ferroelectric Litao3
(Taylor & Francis Ltd, 2019) Yurtseven, Hamit; Kiraci, Ali; 42475; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
The temperature dependences of the damping constant and the relaxation time are calculated by using the Raman frequencies of a* and the lowest A(1) (TO) phonons in the ferroelectric phase close to the ferroelectric-paraelectric transition in LiTaO3 (T-C = 963 K). Both calculations are performed by considering the frequency as an order parameter for the pseudospin-phonon (PS) and the energy fluctuation (EF) models using the observed data from the literature. Values of the activation energies of this crystal are also deduced by using both models in this crystal. Our results show that the PS and EF models can describe the observed behavior adequately for the order-disorder transition in LiTaO3.
Citation - Scopus: 1
Phenomenological Approaches on the Nd³⁺ Doped Ferroelectric Labgeo5
(Taylor & Francis Ltd, 2021) Kiraci, A.; Yurtseven, Hamit; Kara, N.; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
Two phenomenological models, namely the compressible Ising model and Landau model, have been used to analyze the specific heat and the dielectric constant data, respectively for the pure and Nd3+ doped LaBGeO5 (LBG) crystals. The critical exponent of the specific heat was extracted in both ferroelectric and paraelectric phases of the crystals studied here within the temperature intervals of [T - T-C vertical bar < 4 K. The extracted values of the critical exponent were then used to predict some thermodynamic quantities such as the enthalpy, entropy, and the Gibbs free energy. Regarding the analysis of dielectric constant data within the framework of the Landau theory, the observed values of the birefringence were associated with the order parameter below the transition temperature T-c. The Landau coefficients a(0) and a(4) were determined. Our results indicate a second-order phase transition mechanism.
Pressure and Temperature Dependence of the Dielectric Properties in Barium Titanate
(Indian Academy of Sciences, 2025) Kiraci, Ali; Yurtseven, Hamit; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
Temperature and pressure dependences of the soft-mode frequency (omega) and the dielectric constant (epsilon) are studied for the tetragonal-cubic transition (T-C = 395 K) in BaTiO3. We find that variations of the frequency and the dielectric constant with the temperature (pressure) are related to each other linearly close to the phase transition in this ferroelectric material. Instead of the Curie-Weiss behaviour of the dielectric constant, the critical behaviour of both soft-mode frequency and the dielectric constant is expressed by the power-law formulae, and the critical exponents are determined using the observed data from the literature. Our predicted frequencies of the soft mode at various pressures and temperatures, can be examined by the experimental measurements close to the tetragonal-cubic transition in BaTiO3.
Citation - WoS: 1
Citation - Scopus: 1
Pressure Dependence of the Raman Frequency Calculated From the Volume Data Close To the Ferroelectric-Paraelectric Transition in Pbtio3
(Taylor & Francis Ltd, 2017) Kiraci, Ali; Yurtseven, Hamit; 42475; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
We calculate the pressure dependence of the Raman frequencies of some Raman modes by using the observed volume data through the mode Gruneisen parameters for the ferroelectri-paraelectric transition in PbTiO3. The mode Gruneisen parameters which we have determined using the observed Raman frequencies for the soft modes, increase considerably with increasing pressure toward the transition pressure (PC similar to 11 GPa) from the tetragonal (ferroelectric) to the cubic (paraelectric) phase in PbTiO3. Variation of the mode Gruneisen parameter with the pressure is rather smooth for the other Raman modes studied as compared to the drastic change at PC for the soft modes in this ferroelectric material. Raman frequencies (energy shifts) of the modes which we have calculated, decrease from the ferroelectric to the paraelectric phase with the exception of the optical modes of E(3LO) and E(3TO) whose Raman frequencies increase with increasing pressure. This decrease and/or increase in the energy shifts for the Raman modes which we have calculated as also observed experimentally, shows a continuous manner, indicating a second order character rather that the first order transition from the tetragonal to the cubic phase in PbTiO3.
Citation - WoS: 6
Citation - Scopus: 5
Pressure-Dependent Raman Modes Near the Cubic-Tetragonal Transition in Strontium Titanate
(Wiley, 2018) Yurtseven, Hamit; Kiraci, Ali; 42475; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
The pressure dependence of the Raman frequency shifts of various Raman modes is calculated at room temperature using the volume data from the literature for the cubic-tetragonal transition in SrTiO3. The isothermal mode Gruneisen parameters of those Raman modes are obtained, which decrease with increasing pressure for this molecular crystal. Calculated Raman frequencies are then used to predict the damping constant and the inverse relaxation time of those Raman modes as a function of pressure by means of the pseudospin-phonon (PS) coupled model and the energy fluctuation (EF) model to describe the cubic-tetragonal transition in SrTiO3. Also, the values of the activation energy are extracted for the Raman modes studied using both models (PS and EF). Our predicted damping constant and the inverse relaxation time for the Raman modes, can be compared with the experimental measurements close to the cubic-tetragonal transition in SrTiO3.
Citation - WoS: 1
Citation - Scopus: 2
Thermodynamic and Dielectric Properties of Hexagonal Barium Titanate Near the Phase Transitions
(Iop Publishing Ltd, 2024) Yurtseven, Hamit; Kiraci, Ali; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
The critical behavior of the thermodynamic quantities is studied for the two phase transitions near the transition temperatures (74 K and 222 K) in the hexagonal (h) BaTiO3. A linear relationship has been established between the variations of the frequency shifts and of the dielectric constant by using the literature data in h-BaTiO3. Temperature and pressure dependence of the mode Gr & uuml;neisen parameters ( gamma p and gamma T ) are also described by a power-law formula as the other thermodynamic parameters near Tpt in h-BaTiO3. Our results show that they explain the observed behavior adequately, in particular soft-mode frequency, dielectric constant, thermal expansion, the excess specific heat and the entropy near Tpt in h-BaTiO3. Temperature dependence of the isobaric mode Gr & uuml;neisen parameter ( gamma p ), enthalpy and the Gibbs free energy, which we have evaluated, can be compared with experiments in h-BaTiO3.