Substituent-Controlled Construction of A4b2-Hexaphyrins and A3b-Porphyrins: a Mechanistic Evaluation
| dc.authorid | Cinar, Seda/0000-0001-6591-7141 | |
| dc.authorscopusid | 8205050900 | |
| dc.authorscopusid | 24725732800 | |
| dc.authorscopusid | 6701347391 | |
| dc.authorwosid | Cinar, Seda/Gzl-7892-2022 | |
| dc.contributor.author | Cinar, Seda | |
| dc.contributor.author | Tasgin, Dilek Isik | |
| dc.contributor.author | Unaleroglu, Canan | |
| dc.date.accessioned | 2025-05-11T16:38:56Z | |
| dc.date.available | 2025-05-11T16:38:56Z | |
| dc.date.issued | 2023 | |
| dc.department | Çankaya University | en_US |
| dc.department-temp | [Cinar, Seda; Unaleroglu, Canan] Hacettepe Univ, Dept Chem, Beytepe Campus, TR-06800 Ankara, Turkiye; [Cinar, Seda] Ankara Haci Bayram Veli Univ, Chem Dept, Polatli Campus, TR-06900 Ankara, Turkiye; [Tasgin, Dilek Isik] Cankaya Univ, Intercurricular Courses Dept, Cent Campus, TR-06790 Ankara, Turkiye | en_US |
| dc.description | Cinar, Seda/0000-0001-6591-7141 | en_US |
| dc.description.abstract | A substituent-dependent construction of novel A3B-porphyrins along with A4B2-hexaphyrins was realized by the reactions of N-tosylimines and meso-aryl-substituted tripyrranes in the presence of Cu(OTf)2 as the catalyst. The reaction mechanism of the presented method was studied on model reactions by electrospray-ionization time-of-flight (HRESI-TOF) mass spectral analysis in a timely manner. The analytical results indicated that the observed azafulvene-ended di- and tripyrrolic intermediates are responsible for the formation of porphyrinogen and hexaphyrinogen forms. | en_US |
| dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK) | en_US |
| dc.description.sponsorship | SC thanks The Scientific and Technological Research Council of Turkey (TUBITAK) for doctoral scholarship (2211-C Domestic Ph.D. Scholarship Programme for Priority Areas) . | en_US |
| dc.description.woscitationindex | Science Citation Index Expanded | |
| dc.identifier.doi | 10.3762/bjoc.19.135 | |
| dc.identifier.endpage | 1840 | en_US |
| dc.identifier.issn | 1860-5397 | |
| dc.identifier.pmid | 38090630 | |
| dc.identifier.scopus | 2-s2.0-85180096119 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 1832 | en_US |
| dc.identifier.uri | https://doi.org/10.3762/bjoc.19.135 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12416/9540 | |
| dc.identifier.volume | 19 | en_US |
| dc.identifier.wos | WOS:001120012800001 | |
| dc.identifier.wosquality | Q2 | |
| dc.language.iso | en | en_US |
| dc.publisher | Beilstein-institut | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.scopus.citedbyCount | 0 | |
| dc.subject | A3B-Porphyrin | en_US |
| dc.subject | N-Tosylimine | en_US |
| dc.subject | Cu(Otf)2 Catalysis | en_US |
| dc.subject | Hresi-Tof Analysis | en_US |
| dc.title | Substituent-Controlled Construction of A4b2-Hexaphyrins and A3b-Porphyrins: a Mechanistic Evaluation | en_US |
| dc.type | Article | en_US |
| dc.wos.citedbyCount | 0 | |
| dspace.entity.type | Publication |