Browsing by Author "Kanbur, M"
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Article Citation - WoS: 16Citation - Scopus: 16Comparative Application of Wavelet Approaches To Absorption and Ratio Spectra for the Simultaneous Determination of Diminazene Aceturate and Phenazone in Veterinary Granules for Injection(Govi-verlag Pharmazeutischer verlag Gmbh, 2005) Dinç, E; Baleanu, Dumitru; Kanbur, M; Baleanu, D; 6981; 36107; Matematik; 02.02. Matematik; 02. Fen-Edebiyat Fakültesi; 01. Çankaya ÜniversitesiA comparison of two wavelet approaches, Daubechies and reverse Biorthogonal, is described for the quantitative resolution of a binary mixture of diminazene aceturate (DIMA) and phenazone (PHE) in veterinary granules for injection without any chemical separation. These two approaches were specified as db4 (a = 180) and rbior3.7 (a = 125) respectively, after testing the signal analysis parameters for the overlapping absorption spectra and ratio spectra. In the first step db4 (a = 180) was applied to the original absorbance data vector of DIMA and PHE. In the second step rbio3.7 (a = 125) was applied to the ratio spectra data vectors of DIMA using the divisor PHE. The same approach was also subjected to the ratio spectra of PHE using the divisor DIMA. The db4 (a = 180) and rbior3.7 (a = 125) calibration graphs were constructed using the transformation values obtained in the wavelet domain. In the method validation, the wavelet calibration functions were tested using synthetic mixtures and the standard addition technique. The simultaneous quantitative analysis of DIMA and PHE in the commercial veterinary preparation was achieved by the elaborated methods. The assay results were compared with each other and good agreement was observed.Article Citation - WoS: 6Citation - Scopus: 7Spectrophotometric Multicomponent Determination of Tetramethrin, Propoxur and Piperonyl Butoxide in Insecticide Formulation by Principal Component Regression and Partial Least Squares Techniques With Continuous Wavelet Transform(Spectroscopy Soc Canada, Ottawa, 2004) Dinç, E; Baleanu, Dumitru; Baleanu, D; Kanbur, M; 56389; Matematik; 02.02. Matematik; 02. Fen-Edebiyat Fakültesi; 01. Çankaya ÜniversitesiA continuous wavelet transform (CWT) followed by a principal component regression(PCR) and partial least squares (PLS) were applied for the quantitative determination of tetramethrin (TRM), propoxur (PPS) and piperonil butoxide (PPR) in their formulations. Absorbances of the concentration set formed by TRM, PPS and PPR mixtures were measured at 850 points between 220-350 nm with 0.1 nm intervals, and their absorbance values as absorbance data vectors were transferred into the wavelets domain. A CWT was applied to the absorbance data. The resulting CWT-coefficients (x-block) and concentration set (y-block) were used for the construction of CWT-PCR and CWT-PLS calibrations. The combination of both continuous wavelet and chemometrics techniques indicates good results for the determination of insecticide in synthetic mixtures and commercial formulation.
