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Browsing by Author "Sikan, F."

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    Article
    Citation - WoS: 16
    Citation - Scopus: 19
    Effect of Sm on Crystallization Kinetics of Cu-Zr Metallic Glasses
    (Elsevier, 2020) Sikan, F.; Polat, G.; Kalay, I.; Kalay, Y. E.; 5743
    The effect of Sm micro-alloying on non-isothermal and isothermal crystallization kinetics of (Zr50Cu40Al10)(100-x)Sm-x (x = 0, 2, 4 at. % Sm) alloys were investigated using differential scanning calorimetry (DSC), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Crystallization activation energies for each composition were calculated in non-isothermal conditions using Kissinger and Ozawa methods and in isothermal conditions using Johnson-Mehl-Avrami model. XRD analysis showed that crystallization product Cu10Zr7 changes to Cu2Sm with Sm presence in isothermal conditions. Both isothermal and isochronal calculations yield that the energy barrier for crystallization has increased with Sm addition. On the other hand, crystallization point drops to lower temperature at the expense of an increase in the pre-exponential factor. The Avrami exponents for all compositions were found to be below 2.5, indicating that crystallization was governed by a diffusion-controlled three-dimensional growth with a decreasing nucleation rate. The apparent increase in crystallization activation energies with increasing Sm content can be one of the affecting factors for commonly held idea of increased glass forming ability for rare-earth containing Zr-based metallic glasses.
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    Article
    Citation - WoS: 8
    Citation - Scopus: 9
    Effect of Sm on Thermal and Mechanical Properties of Cu-Zr Bulk Metallic Glasses
    (Elsevier Science Sa, 2019) Sikan, F.; Atabay, S. E.; Motallebzadeh, A.; Ozerinc, S.; Kalay, I.; Kalay, Y. E.; 101579
    The effect of rare-earth (Sm) microalloying on the thermal stability and phase selection along with the effect of nanocrystallization on the mechanical properties of amorphous melt-spun ribbons of Zr50Cu40Al10, Zr49Cu39.2Al9.8Sm2 and Zr48Cu38.4Al9.6Sm4 alloys were investigated using differential scanning calorimetry (DSC), X-ray diffraction (XRD), transmission electron microscopy (TEM), Vickers and nanoindentation hardness tests and micropillar compression analysis. XRD and TEM analyses showed that all samples were fully amorphous in as-spun state; however, crystallization sequences for the Sm-free and the Sm micro-alloyed samples were different during devitrification. Combined study of XRD, DSC and TEM on melt-spun ribbons show that Zr48Cu38.4Al9.6Sm4 have nanocrystallization of Cu2Sm phase with an average diameter of 10 nm, which was absent in Zr50Cu40Al10, prior to crystallization of Cu10Zr7 phase. The nanoindentation and micropillar compression tests revealed Cu2Sm nanocrystals embedded in Zr48Cu38.4Al9.6Sm4 alloy improves strength and hardness. On the other hand, presence of these nanocrystals deteriorate shear band stability and thus result in a catastrophic brittle fracture through a single shear band burst.