Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12416/8651
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Article Analysis and Mathematical Computation of Some Dynamic Functions for the Guanidine Zinc Sulfate(Taylor & Francis Ltd, 2021) Askun, A. R.; Kiraci, A.A power-law formula with a critical exponent alpha was used to analyze the anomalous behavior of the specific heat for guanidine zinc sulfate (GZS) crystal close to the phase transition temperature of T-c = 178.4 K. The obtained values of 0.13 and 0.14 for alpha below (T < T-c) and above (T> T-c) the phase transition temperature, respectively, were almost the same value of 0.13 (1/8) that predicted from the 3-D (sing model. Also, the internal energy U, the entropy S and the free energy G of this crystal were calculated as a function of temperature dose to the phase transition temperature of T-c = 178.4 K.Article Citation - WoS: 2Citation - Scopus: 3A Phenomenological Study on Ferroelectric Β-Glycine(Taylor & Francis Ltd, 2021) Kiraci, A.The anomalous behavior of the specific heat for beta-glycine was analyzed in terms of the compressible Ising model approximately 5 K below and above the ferrelectric-paraelectric phase transition temperature of T-C =252 K. The obtained value of the critical exponent alpha =0.12 in the ferroelectric phase (T < TC) was consistent with that predicted from the 3-d Ising model (alpha =0.13), while the obtained value of alpha =0.32 in the paraelectric phase (T > TC) was consistent with that predicted from the 2-d potts model (alpha =0.30). Some thermodynamic quantities such as the internal energy, the entropy and the free energy of beta-glycine were then predicted in terms of these extracted values of the critical exponents close to the phase transition temperature of TC. Our calculated values of the thermodynamic quantities are in good agreement with the observed data.Article Citation - Scopus: 1Phenomenological Approaches on the Nd<sup>3+</Sup> Doped Ferroelectric Labgeo5(Taylor & Francis Ltd, 2021) Kiraci, A.; Yurtseven, Hamit; Kara, N.Two phenomenological models, namely the compressible Ising model and Landau model, have been used to analyze the specific heat and the dielectric constant data, respectively for the pure and Nd3+ doped LaBGeO5 (LBG) crystals. The critical exponent of the specific heat was extracted in both ferroelectric and paraelectric phases of the crystals studied here within the temperature intervals of [T - T-C vertical bar < 4 K. The extracted values of the critical exponent were then used to predict some thermodynamic quantities such as the enthalpy, entropy, and the Gibbs free energy. Regarding the analysis of dielectric constant data within the framework of the Landau theory, the observed values of the birefringence were associated with the order parameter below the transition temperature T-c. The Landau coefficients a(0) and a(4) were determined. Our results indicate a second-order phase transition mechanism.Article Citation - WoS: 8Citation - Scopus: 8Analysis of the Specific Heat and the Free Energy of [N(ch3)4]2znbr4 Close To the Ferro-Paraelastic Phase Transition(Taylor & Francis Ltd, 2019) Kiraci, A.A power-law formula deduced from the Ising model was used to analyze the temperature dependence of the specific heat and the Gibbs free energy of [N(CH3)(4)](2)ZnBr4 compound in the vicinity of the phase transition temperature of T-C = 287.2 K. Obtained values of the critical exponents from the Gibbs free energy were consistent with that predicted from 2-d potts model ( = 0.3), while obtained values of from the specific heat in both ferroelastic and paraelastic phases were consistent with that predicted from the mean field theory ( = 0) in the vicinity of the phase transition temperature. This is an indication of that [N(CH3)(4)](2)ZnBr4 compound undergoes a second order type phase transition. Also, the enthalpy () and the entropy () of this crystal were calculated in terms of the extracted values of the critical exponent in both ferroelastic and paraelastic phases.Article Analysis of the Specific Heat and the Free Energy and Calculation of the Entropy and the Internal Energy of [N(ch3)4]2mnbr4 Close To the Phase Transition(Taylor & Francis Ltd, 2021) Kiraci, A.The critical behavior of the specific heat and the Gibbs free energy of [N(CH3)(4)](2)MnBr4 was analyzed using the 'sing model close to the phase transition temperature of T-c = 276.5 K. Obtained value of alpha=0.02 from the Gibbs free energy and from the specific heat approximately 2.0 K and 1.4 K, respectively, below Tc (ferroelastic phase) and also deduced value of alpha= 0.04 from the specific heat approximately 0.3 K above T-c (paraelastic phase) can be compared with that predicted from mean field theory (alpha = 0). Also, the entropy and the internal energy of this crystal were predicted.