WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12416/8653
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Article Citation - WoS: 49Citation - Scopus: 51Multidetermination of Thiamine Hcl and Pyridoxine Hcl in Their Mixture Using Continuous Daubechies and Biorthogonal Wavelet Analysis(Elsevier Science Bv, 2003) Baleanu, D; Dinç, EA new graphical method based on the one-dimensional wavelet transform (WT) was proposed and tested on mixture of thiamine hydrochloride (THI) and pyridoxine hydrochloride (PYR) in the presence of strongly overlapping signals. We selected from the data of the UV-VIS absorption spectra a signal consisting of 1150 points corresponding to the concentration range 8-32 mg ml(-1) for each vitamin and we subjected it to Daubechies8 (DAUB8) and Biorthogonal6.8 (BIOR6.8) wavelet transforms. Since the peaks of the transformed signals were bigger than original ones a zero crossing method was applied to obtain the calibration graphs. In addition, the validity of Beer-Lambert law was assumed for the transformed signals. An appropriate scale setting was choosing to obtain an alternative calibration for each method. MATLAB 6.5 software was used for one-dimensional wavelet analysis and the basic concepts about wavelet method were given. The obtained results were successfully compared among each other as well as with those obtained by other literature methods. The method developed in this paper is rapid, easy to apply, not expensive and it is suitable for analyzing of the overlapping signals of compounds in their mixtures without any chemical pre-treatment. (C) 2002 Elsevier Science B.V. All rights reserved.Article Citation - WoS: 72Citation - Scopus: 81An Application of Derivative and Continuous Wavelet Transforms To the Overlapping Ratio Spectra for the Quantitative Multiresolution of a Ternary Mixture of Paracetamol, Acetylsalicylic Acid and Caffeine in Tablets(Elsevier Science Bv, 2005) Özdemir, A; Baleanu, D; Dinç, EQuantitative multi resolution of tablets and ternary mixtures of paracetamol (PAR), acetylsalicylic acid (ASP) and caffeine (CAF) having strongly overlapping spectra was accomplished by two graphical transform methods as ratio spectra first derivative-zero crossing and ratio spectra-continuous wavelet transform-zero crossing (ratio spectra CWT-zero crossing) methods. In this study, ratio spectra derivative-zero crossing and ratio spectra CWT-zero crossing methods are based on the use of transformed signals of the ratio spectra and their calibration graphs were obtained by measuring the dA/dlambda and CWT amplitudes of the ratio spectra corresponding to zero crossing points. For the comparison purpose. PLS calibration method was applied to predict the content of the same mixtures containing the subject active Compounds. The obtained calibrations were tested by using the synthetic mixtures and standard addition technique and they applied to the simultaneous determination of PAR, ASP and CAF in commercial pharmaceutical preparation. The obtained results were statistically compared with each other as well as those obtained by HPLC method and they showed good agreement. (C) 2004 Published by Elsevier B.V.