WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12416/8653
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Article Citation - WoS: 56Citation - Scopus: 56Application of the Wavelet Method for the Simultaneous Quantitative Determination of Benazepril and Hydrochlorothiazide in Their Mixtures(Aoac int, 2004) Baleanu, D; Dinç, EThe discrete and continuous wavelet transforms were applied to the overlapping signal analysis of the ratio data signal for simultaneous quantitative determination of the title subject compounds in samples. The ratio spectra data of the binary mixtures containing benazepril (BE) and hydrochlorothiazide (HCT) were transferred as data vectors into the wavelet domain. Signal compression, followed by a 1-dimension continuous wavelet transform (CWT), was used to obtain coincident transformed signals for pure BE and HCT and their mixtures. The coincident transformed amplitudes corresponding to both maximum and minimum points allowed construction of calibration graphs for each compound in the binary mixture. The validity of CWT calibrations was tested by analyzing synthetic mixtures of the investigated compounds, and successful results were obtained. All calculations were performed within EXCEL, C++, and MATLAB6.5 softwares. The obtained results indicated that our approach was flexible and applicable for the binary mixture analysis.Article Citation - WoS: 53Citation - Scopus: 56Multicomponent Quantitative Resolution of Binary Mixtures by Using Continuous Wavelet Transform(Oxford Univ Press inc, 2004) Baleanu, D; Dinc, EContinuous 1-dimensional wavelet transform (WT) was applied to the quantitative analysis of a vitamin combination of thiamine hydrochloride (THI) and pyridoxine hydrochloride (PYR) with strongly overlapping signals. Absorbance data from the UV-Vis absorption spectrum of width 1150 were subjected to Gauss1 and Gauss2 WTs. Because of its flexibility, data processing, and its high signal amplitude, the continuous WT method is a powerful tool for analysis of multicomponent mixtures. By measuring the amplitude signals corresponding to the selected zero-crossing points of the transformed signal, we obtained the calibration curve. The validation of the calibration graphs was confirmed with different mixtures of THI and PYR at various concentration ratios. A brief explanation of the continuous wavelet method is given. MATLAB 6.5 software was used to perform the calculations. The results of our study were compared with those obtained by spectroscopic, chemometric, and liquid chromatographic methods, and good agreement was found.Article Citation - WoS: 1Citation - Scopus: 1Hamilton-Jacobi Quantization of Systems With Time-Dependent Constraints(Kluwer Academic/plenum Publ, 2002) Baleanu, D; Güler, YHamilton-Jacobi formalism is used to investigate time-dependent constraint systems. It is proved that the generalization of Dirac's canonical quantization method in the nonstationary case can be obtained naturally in Hamilton-Jacobi formalism. The example of the relativistic particle in a plane wave is analyzed in detail.Article Citation - WoS: 6Citation - Scopus: 4Symmetries of the Dual Metrics(World Scientific Publ Co Pte Ltd, 2002) Baleanu, DIn this paper the symmetries of the dual manifold are investigated. We found the conditions when the manifold and its dual admit the same Killing vectors and Killing-Yano tensors. The dual conformal Killing vectors and dual conformal Killing-Yano tensors were investigated. In the case of an Einstein's metric g(munu) the corresponding equations for its dual were found. The examples of Kerr-Newman geometry and the separable coordinates in 1 + 1 dimensions axe analyzed in details.Article Citation - WoS: 20Citation - Scopus: 22Simultaneous Spectrophotometric Analysis of Codeine Phosphate, Acetylsalicylic Acid, and Caffeine in Tablets by Inverse Least-Squares and Principal Component Regression Techniques(Taylor & Francis inc, 2002) Baleanu, D; Onur, F; Dinç, EInverse least-squares (ILS) and principal component regression (PCR) techniques were proposed for the spectrophotometric simultaneous analysis of ternary mixture containing codeine phosphate, acetylsalicylic acid and caffeine without any pretreatment. A training set of the title drugs was randomly prepared for both techniques. The absorbance values were measured at the 15 points in the wavelength range 220-290 nm for the absorption spectra. The ILS and PCR calibrations were constructed by using their algorithms and they were tested for the synthetic mixtures of three drugs. Means recoveries and relative standard deviations for ILS and PCR were found as 100.2 and 1.23%, 99.5 and 2.10% for codeine phosphate, 100.5 and 1.30%, 100.3 and 1.18% for acetylsalicylic acid and 99.4 and 1.33%, 99.3 and 1.31% for caffeine, respectively. We realised the numerical computations by using the 'Maple V' software. The results were successfully observed by applying the chemometric techniques to the tablets, and a good agreement was found between the obtained values and the indicated quantities of the pharmaceutical formulation marketed in Turkey.Article Citation - WoS: 54Citation - Scopus: 59An Approach To Quantitative Two-Component Analysis of a Mixture Containing Hydrochlorothiazide and Spironolactone in Tablets by One-Dimensional Continuous Daubechies and Biorthogonal Wavelet Analysis of Uv-Spectra(Taylor & Francis inc, 2003) Baleanu, D; Üstündag, Ö; Dinç, EIn this study a new method of quantitative two-component analysis of a mixture of hydrochlorothiazide (HCT) and spironolactone (SP) in the presence of strongly overlapping signals was achieved by using one-dimensional continuous wavelet analysis. This new method was built on the simultaneous use of both continuous wavelet transform and the zero crossing technique for the quantitative resolution of this binary mixture. A series of solutions, in the concentration range of 2-22 mg/ml for both compounds, in methanol and 0.2 M sodium acetate buffer, pH = 5 (20:80), were considered. The absorption spectra of the standard solutions were recorded in the wavelength range of 215-330 nm. To apply our methods we selected 400 points from the absorption spectra and we subjected the corresponding signal to Daubechies2 (DAUB2) and Biorthogonal1.5 (BIOR1.5) one-dimensional wavelet transform. In the transformed signals, the amplitude of HCT was measured at the position of a zero crossing point of SP and vice versa. Thus simple linear regression analysis can be applied to establish calibrations for both components. These calibrations were validated with synthetic mixtures of HCT and SP. MATLAB 6.5 software was used for one-dimensional wavelet analysis, and the basic concepts about wavelet method are briefly explained. The method developed in this paper is rapid, easy to apply, inexpensive and it is suitable for analysis of the overlapping signals of compounds in their mixtures without any chemical pre-treatment.Article Citation - WoS: 11Citation - Scopus: 9Dual Metrics and Nongeneric Supersymmetries for a Class of Siklos Space-Times(World Scientific Publ Co Pte Ltd, 2002) Baskal, S; Baleanu, DThe presence of Killing-Yano tensors implies the existence of nongeneric supercharges in spinning point particle theories on curved backgrounds. Dual metrics axe defined through their associated nondegenerate Killing tensors of valence two. Siklos space-times, which are the only nontrivial Einstein spares conformal to nonflat pp-waves are investigated with regard to the existence of their corresponding Killing and Killing-Yano, tensors. It is found that a class of Siklos space-times admit dual metrics and nongeneric supercharges.Article Citation - WoS: 3Citation - Scopus: 2Hamilton-Jacobi Treatment of Chiral Schwinger Model(Kluwer Academic/plenum Publ, 2001) Güler, Y; Baleanu, DWe investigate the path integral quantization of the bosonic chiral Schwinger model using multi-Hamilton-Jacobi procedure. The integrability conditions require the extension of the initial phase space. The Wess-Zumino term was recovered calculating the action corresponding to the extended system.Article Citation - WoS: 14Citation - Scopus: 14The Hamilton-Jacobi Treatment of Supersymmetric Quantum Mechanics(World Scientific Publ Co Pte Ltd, 2001) Baleanu, D; Güler, YWe study the Hamilton-Jacobi quantization of supersymmetric quantum mechanics. The equations of motion of the Grassmann variables are obtained from the integrability conditions. The results are in agreement with those obtained by Dirac's procedure.Article Citation - WoS: 34Chemometric Quantitative Analysis of Pyridoxine Hcl and Thiamine Hcl in a Vitamin Combination by Principal Component Analysis, Classical Least Squares, and Inverse Least Squares Techniques(Marcel dekker inc, 2001) Baleanu, D; Onur, F; Dinç, EThree chemometric techniques were described for the analysis of pyridoxine hydrochloride and thiamine hydrochloride within a vitamin combination in the presence of spectral interferences. For these techniques, the training set was prepared by using synthetic mixtures containing two vitamins in multiple possible combinations for the range of 8-40 mu /mL in 0.1 M HCl. The absorbance values for the training set were obtained by direct measurements at 18 wavelengths in the region 222-305 nm for the zero order spectra. The numerical values were calculated by using the 'Maple V' software. Mean recoveries and relative standard deviations for the principal component analysis, classical least squares and inverse least squares techniques were found as 100.7% and 0.95%; 100.5% and 1.38% and, 99.3% and 1.04 for pyridoxine hydrochloride; and 99.7% and 1.03%; 99.1% and 1.05% and, 99.6% and 1.58% for thiamine hydrochloride, respectively. These three chemometric techniques were successfully applied to vitamin tablets marketed in Turkey. The results were compared with each other and good coincidence was observed.