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Characterization approach to modified glassy carbon electrode-nanofilm system within multidimensional scaling

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2011

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Amer Scientific Publishers

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Abstract

The aim of this work is to characterize the nanofilm consisting of the benzoic acid-modified glassy carbon (GC) electrode system through multidimensional scaling space analysis. The surface modification is based on the electrochemical reaction between the GC electrode and benzoic acid-diazonium salt (BA-DAS). As a result, the nonofilms regarding the benzoic acid-glassy carbon (BA-GC) electrode surface was obtained. For the analysis of the naonfilm of BC-GC electrode system, the IR spectra of the modified BA-GC electrode surface, GC surface and BA-DAS were recorded in the spectral range of 599.84 - 3996.34 [cm(-1)]. The IR data vectors of the above three forms were processed by the using the multidimensional scaling space approach to demonstrate the existence of a nanofilm on the modified BA-GC electrode system. Two- and three-dimensional MDS profiles obtained by application of multidimensional scaling approach to the data sets {CG1, ... ,CG10}, {BA-GC1, ... ,BA-GC10} and {FILM1, ... ,FILM10} allow a good recognition of the nanofilm on the modified glassy carbon (GC) electrode system

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Multidimensional Scaling, Quantitative Recognition, Nanofilm, Modified Glassy Carbon Electrode-Nanofilm System

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Citation

Tenreiro Machado, J.A...et al. (2011). Characterization approach to modified glassy carbon electrode-nanofilm system within multidimensional scaling. Journal of Computational and Theoretical Nanoscience, 8(2), 268-273. http://dx.doi.org/10.1166/jctn.2011.1688

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Journal of Computational and Theoretical Nanoscience

Volume

8

Issue

2

Start Page

268

End Page

273