Bilgilendirme: Sürüm Güncellemesi ve versiyon yükseltmesi nedeniyle, geçici süreyle zaman zaman kesintiler yaşanabilir ve veri içeriğinde değişkenlikler gözlemlenebilir. Göstereceğiniz anlayış için teşekkür ederiz.
 

Kimya Bilim Dalı

Permanent URI for this collectionhttps://hdl.handle.net/20.500.12416/2168

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  • Article
    Citation - WoS: 5
    Citation - Scopus: 6
    Ring Annulation Versus Alkylation of Pyrrole With Α-Phosphoryl Ketones
    (Pergamon-elsevier Science Ltd, 2016) Tasgin, Dilek Isik; Unaleroglu, Canan; 16910; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
    In this study; novel aryl, heteroaryl, pyrrolyl and phosphoryl groups containing pyrrolizines were synthesized by the ring annulation reaction of aryl or heteroaryl substituted alpha-phosphoryl-alpha,beta-unsaturated ketones with pyrrole under mild reaction conditions. This domino reaction involves scandium triflate catalyzed addition of pyrrole to the double bond of alpha-phosphoryl-alpha,beta-unsaturated ketones, carbonyl group and finally ring annulation sequences. The presented work provided a convenient way for the synthesis of novel bispyrrolic compounds. (C) 2016 Elsevier Ltd. All rights reserved.
  • Article
    Citation - WoS: 3
    Citation - Scopus: 3
    N-Phosphorylation of Pyrroles: an Intramolecular Migration Reaction
    (Pergamon-elsevier Science Ltd, 2018) Unaleroglu, Canan; Tasgin, Dilek Isik; 09.01. Ortak Dersler Bölümü; 09. Rektörlük; 01. Çankaya Üniversitesi
    A new synthetic method is reported for the N-phosphorylation of pyrroles via intramolecular migration of a phosphonate diester group. The reaction proceeds under mild conditions and produces N-phosphorylated pyrrole derivatives in moderate to good yields. (C) 2018 Elsevier Ltd. All rights reserved.