Kiracı, Ali
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Kiraci, A.
Kiraci, Ali
Kıracı, Ali
Kiraci, Ali
Kıracı, Ali
Job Title
Prof. Dr.
Email Address
akiraci@cankaya.edu.tr
Main Affiliation
09.01. Ortak Dersler Bölümü
Ortak Dersler Bölümü
09. Rektörlük
01. Çankaya Üniversitesi
Ortak Dersler Bölümü
09. Rektörlük
01. Çankaya Üniversitesi
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Current Staff
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Documents
39
Citations
185
h-index
8
Documents
37
Citations
182
Scholarly Output
35
Articles
33
Views / Downloads
2026/2546
Supervised MSc Theses
0
Supervised PhD Theses
0
WoS Citation Count
85
Scopus Citation Count
87
WoS h-index
6
Scopus h-index
5
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0
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0
WoS Citations per Publication
2.43
Scopus Citations per Publication
2.49
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5
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0
Google Analytics Visitor Traffic
| Journal | Count |
|---|---|
| Ferroelectrics | 9 |
| Optik | 4 |
| Phase Transitions | 3 |
| IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control | 2 |
| Joint IEEE International Symposium on the Applications of Ferroelectric / International Symposium on Integrated Functionalities / Piezoelectric Force Microscopy Workshop (ISAF/ISIF/PFM) -- MAY 24-27, 2015 -- Singapore, SINGAPORE | 1 |
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35 results
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Now showing 1 - 10 of 35
Article Citation - WoS: 2Citation - Scopus: 3A Phenomenological Study on Ferroelectric Β-Glycine(Taylor & Francis Ltd, 2021) Kiraci, A.The anomalous behavior of the specific heat for beta-glycine was analyzed in terms of the compressible Ising model approximately 5 K below and above the ferrelectric-paraelectric phase transition temperature of T-C =252 K. The obtained value of the critical exponent alpha =0.12 in the ferroelectric phase (T < TC) was consistent with that predicted from the 3-d Ising model (alpha =0.13), while the obtained value of alpha =0.32 in the paraelectric phase (T > TC) was consistent with that predicted from the 2-d potts model (alpha =0.30). Some thermodynamic quantities such as the internal energy, the entropy and the free energy of beta-glycine were then predicted in terms of these extracted values of the critical exponents close to the phase transition temperature of TC. Our calculated values of the thermodynamic quantities are in good agreement with the observed data.Article Dielectric and Thermal Properties of the Ferroelectric NH4HSO4 Close to Phase Transitions(Elsevier, 2025) Kiraci, A.; Yurtseven, H.This work gives the analysis of the dielectric and thermal properties close to the second order and first order types of ferroelectric-paraelectric phase transitions in ferroelectrics, in particular, NH4HSO4. The power-law formula is used by adapting the Kouvel-Fisher (KF) method describing the magnetization (M) and magnetic susceptibility (chi M) in the case of the spontaneous polarization (PS) and the dielectric constant (& varepsilon;), respectively, in ferroelectric systems. Similar treatment is performed to describe the heat capacity (CP) and the thermal expansivity (proportional to P) close to the phase transitions in NH4HSO4. We show that the variations of PS and & varepsilon; with the temperature near the upper Curie point (TC1 = 270 K) exhibit linearity for the second order transition in NH4HSO4. A linear variation is also obtained between the CP and proportional to P with the temperature close to the lower Curie point (TC2 = 160 K) for the first order transition in this crystal. Experimental data are used from the literature for our analysis. Our approach given here to describe dielectric and thermal properties of NH4HSO4 close to the Curie points, can be applied to some other ferroelectric materials.Article Citation - WoS: 1Citation - Scopus: 1Pressure Dependence of the Raman Frequency Calculated From the Volume Data Close To the Ferroelectric-Paraelectric Transition in Pbtio3(Taylor & Francis Ltd, 2017) Kiraci, Ali; Yurtseven, HamitWe calculate the pressure dependence of the Raman frequencies of some Raman modes by using the observed volume data through the mode Gruneisen parameters for the ferroelectri-paraelectric transition in PbTiO3. The mode Gruneisen parameters which we have determined using the observed Raman frequencies for the soft modes, increase considerably with increasing pressure toward the transition pressure (PC similar to 11 GPa) from the tetragonal (ferroelectric) to the cubic (paraelectric) phase in PbTiO3. Variation of the mode Gruneisen parameter with the pressure is rather smooth for the other Raman modes studied as compared to the drastic change at PC for the soft modes in this ferroelectric material. Raman frequencies (energy shifts) of the modes which we have calculated, decrease from the ferroelectric to the paraelectric phase with the exception of the optical modes of E(3LO) and E(3TO) whose Raman frequencies increase with increasing pressure. This decrease and/or increase in the energy shifts for the Raman modes which we have calculated as also observed experimentally, shows a continuous manner, indicating a second order character rather that the first order transition from the tetragonal to the cubic phase in PbTiO3.Article Citation - WoS: 1Citation - Scopus: 2Thermodynamic and Dielectric Properties of Hexagonal Barium Titanate Near the Phase Transitions(Iop Publishing Ltd, 2024) Yurtseven, Hamit; Kiraci, AliThe critical behavior of the thermodynamic quantities is studied for the two phase transitions near the transition temperatures (74 K and 222 K) in the hexagonal (h) BaTiO3. A linear relationship has been established between the variations of the frequency shifts and of the dielectric constant by using the literature data in h-BaTiO3. Temperature and pressure dependence of the mode Gr & uuml;neisen parameters ( gamma p and gamma T ) are also described by a power-law formula as the other thermodynamic parameters near Tpt in h-BaTiO3. Our results show that they explain the observed behavior adequately, in particular soft-mode frequency, dielectric constant, thermal expansion, the excess specific heat and the entropy near Tpt in h-BaTiO3. Temperature dependence of the isobaric mode Gr & uuml;neisen parameter ( gamma p ), enthalpy and the Gibbs free energy, which we have evaluated, can be compared with experiments in h-BaTiO3.Article Citation - WoS: 8Citation - Scopus: 8Analysis of the Specific Heat and the Free Energy of [N(ch3)4]2znbr4 Close To the Ferro-Paraelastic Phase Transition(Taylor & Francis Ltd, 2019) Kiraci, A.A power-law formula deduced from the Ising model was used to analyze the temperature dependence of the specific heat and the Gibbs free energy of [N(CH3)(4)](2)ZnBr4 compound in the vicinity of the phase transition temperature of T-C = 287.2 K. Obtained values of the critical exponents from the Gibbs free energy were consistent with that predicted from 2-d potts model ( = 0.3), while obtained values of from the specific heat in both ferroelastic and paraelastic phases were consistent with that predicted from the mean field theory ( = 0) in the vicinity of the phase transition temperature. This is an indication of that [N(CH3)(4)](2)ZnBr4 compound undergoes a second order type phase transition. Also, the enthalpy () and the entropy () of this crystal were calculated in terms of the extracted values of the critical exponent in both ferroelastic and paraelastic phases.Article Citation - WoS: 1Citation - Scopus: 1Calculation of the Spin-Lattice Relaxation Time and the Activation Energy Near the Iv-Iii Phase Transition in Pyridinium Fluorosulfonate (C5nh6)fso3(Taylor & Francis Ltd, 2022) Kara, N.; Kiraci, A.; Yurtseven, HamitThe spin-lattice relaxation time T-1(H) for protons nuclei is calculated in term of the pseudospin-phonon (PS) coupled and the energy fluctuation (EF) models close to the IV-III solid-solid phase transition of T-C = 235 K in (C5NH6)FSO3. This calculation was performed by associating the observed second moment of the H-1 as the order parameter below k and the disorder parameter above T-C. Values of the activation energy for the cation reorientation in this crystal are also deduced by using both models. In addition, the observed dielectric permittivity of this crystal is analyzed within the framework of the Landau theory and values of the spontaneous polarization (P-s) are determined as a function of temperature. The normalized values of P-s are used in the PS and EF models to extract the activation energy for the reorientation of the dipole moment of this compound arising from cation-anion interaction. Our results show that the PS and EF models can describe the observed behavior of the spin-lattice relaxation time adequately for the IV-III solid-solid transition in (C5NH6)FSO3.Article Citation - Scopus: 1Phenomenological Approaches on the Nd3+ Doped Ferroelectric Labgeo5(Taylor & Francis Ltd, 2021) Kiraci, A.; Yurtseven, Hamit; Kara, N.Two phenomenological models, namely the compressible Ising model and Landau model, have been used to analyze the specific heat and the dielectric constant data, respectively for the pure and Nd3+ doped LaBGeO5 (LBG) crystals. The critical exponent of the specific heat was extracted in both ferroelectric and paraelectric phases of the crystals studied here within the temperature intervals of [T - T-C vertical bar < 4 K. The extracted values of the critical exponent were then used to predict some thermodynamic quantities such as the enthalpy, entropy, and the Gibbs free energy. Regarding the analysis of dielectric constant data within the framework of the Landau theory, the observed values of the birefringence were associated with the order parameter below the transition temperature T-c. The Landau coefficients a(0) and a(4) were determined. Our results indicate a second-order phase transition mechanism.Article Citation - WoS: 6Citation - Scopus: 6A Phenomenological Study on Ferroelectric Pyridinium Tetrafluoroborate (C5nh6) Bf4(Elsevier, 2019) Kiraci, A.The temperature dependence of the specific heat C-V of (C5NH6)BF4 was analyzed according to a power law formula with a critical exponent alpha deduced from the compressible Ising model in the vicinity of the phase transition temperatures of T-C1 = 238 K and T-C2 = 204 K. The extracted values of the critical exponent alpha within the temperature intervals of vertical bar T - T-C1 vertical bar < 6 K and also T - T-C2 < 6 K were consistent with that predicted from the 3d-Ising model (alpha = 0.10) while obtained values of alpha within the temperature interval of T-C2 - T < 6 K were consistent with that predicted from 2-d potts model (alpha = 0.30). In addition, the thermodynamic quantities: the internal energy (U), the entropy (S) and the Helmholtz free energy (F) of this compound were calculated on the basis of the extracted values of the critical exponent a below and above the phase transition temperatures of T-C1 and T-C2.Article Analysis of the Specific Heat and the Free Energy and Calculation of the Entropy and the Internal Energy of [N(ch3)4]2mnbr4 Close To the Phase Transition(Taylor & Francis Ltd, 2021) Kiraci, A.The critical behavior of the specific heat and the Gibbs free energy of [N(CH3)(4)](2)MnBr4 was analyzed using the 'sing model close to the phase transition temperature of T-c = 276.5 K. Obtained value of alpha=0.02 from the Gibbs free energy and from the specific heat approximately 2.0 K and 1.4 K, respectively, below Tc (ferroelastic phase) and also deduced value of alpha= 0.04 from the specific heat approximately 0.3 K above T-c (paraelastic phase) can be compared with that predicted from mean field theory (alpha = 0). Also, the entropy and the internal energy of this crystal were predicted.Article Citation - WoS: 3Citation - Scopus: 3A Phenomenological Study on Ferroelastic Kh3(Seo3)2 and Kd3(Seo3)2(Pergamon-elsevier Science Ltd, 2021) Kiraci, A.The anomalous behavior of the Brillouin frequency shift omega of the soft acoustic mode for KH3(SeO3)(2) and KD3(SeO3)(2), and also the volume thermal expansion proportional to(V) and the specific heat C of KH3(SeO3)(2) have been analyzed for various temperature intervals close to the phase transition temperatures TC at around 211 K and 302 K, respectively. Our extracted values of the critical exponent from C and proportional to(V) of KH3(SeO3)(2) within the temperature intervals of vertical bar T -T-C vertical bar < 7 K are nearly zero, while the critical exponent extracted from the Brillouin frequency shift data of both KH3(SeO3)(2) and KD3(SeO3)(2) within the same temperature interval of vertical bar T -T-C vertical bar < 7 K decrease very rapidly toward to zero as the phase transition temperatures are approached. Our results indicate that the critical behavior of omega, proportional to(V) and C of both KH3(SeO3)(2) and KD3(SeO3)(2) can be described with the same critical exponent within the temperature interval of vertical bar T -T-C vertical bar < 2 K.
